Publications

2024

Accessing a Highly Reducing Uranium(III) Complex through Cyclometalation

D. K. Modder; R. Scopelliti; M. Mazzanti 

Inorganic Chemistry

2024-01-13

DOI : 10.1021/acs.inorgchem.3c03668

2023

Two-Electron Redox Reactivity of Thorium Supported by Redox-Active Tripodal Frameworks

F-C. Hsueh; D. W. Chen; T. Rajeshkumar; R. Scopelliti; L. Maron et al. 

Angewandte Chemie-International Edition

2023-12-29

DOI : 10.1002/anie.202317346

A trinuclear metallasilsesquioxane of uranium(III)

M. C. G. Tricoire; N. Jori; F. F. Tirani; R. Scopelliti; I. Zivkovic et al. 

Chemical Communications

2023-11-23

Vol. 60 , num. 1, p. 55-58.

DOI : 10.1039/d3cc05390c

Multimetallic Uranium Nitride Cubane Clusters from Dinitrogen Cleavage

M. S. Batov; I. del Rosal; R. Scopelliti; F. Fadaei-Tirani; I. Zivkovic et al. 

Journal Of The American Chemical Society

2023-11-22

Vol. 145 , num. 48, p. 26435-26443.

DOI : 10.1021/jacs.3c10617

Dinitrogen cleavage by a dinuclear uranium(III) complex

N. Jori; M. R. Keener; T. Rajeshkumar; R. Scopelliti; L. Maron et al. 

Chemical Science

2023-11-06

Vol. 14 , num. 46, p. 13485-13494.

DOI : 10.1039/d3sc05253b

Multielectron Redox Chemistry of Uranium by Accessing the plus II Oxidation State and Enabling Reduction to a U(I) Synthon

M. Keener; R. A. K. Shivaraam; T. Rajeshkumar; M. Tricoire; R. Scopelliti et al. 

Journal Of The American Chemical Society

2023-07-13

Vol. 145 , num. 29, p. 16271-16283.

DOI : 10.1021/jacs.3c05626

Isolation and redox reactivity of cerium complexes in four redox states

F-C. Hsueh; T. Rajeshkumar; L. Maron; R. Scopelliti; A. Sienkiewicz et al. 

Chemical Science

2023-05-05

DOI : 10.1039/d3sc01478a

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

R. A. Keerthi Shivaraam; M. Keener; D. K. Modder; T. Rajeshkumar; I. Živković et al. 

Angewandte Chemie International Edition

2023-04-04

Vol. 2023 , p. e202304051.

DOI : 10.1002/anie.202304051

Bonding and Reactivity in Terminal versus Bridging Arenide Complexes of Thorium Acting as Th II Synthons

F-C. Hsueh; T. Rajeshkumar; B. Kooij; R. Scopelliti; K. Severin et al. 

Angewandte Chemie International Edition

2023

num. Angew. Chem. Int. Ed. 2023, 62, e202215846.

DOI : 10.1002/anie.202215846

2022

Coordination Chemistry of Actinides

G. Nocton; M. Mazzanti 

The Lanthanides and Actinides Synthesis, Reactivity, Properties and Applications; World Scientific, 2022-12-04. p. 728.

ISBN : 978-1-800610-15-6

DOI : 10.1142/9781800610163_0005

Assembling diuranium complexes in different states of charge with a bridging redox-active ligand

D. K. Modder; M. S. Batov; T. Rajeshkumar; A. Sienkiewicz; I. Zivkovic et al. 

Chemical Science

2022-08-31

Vol. 13 , num. 38, p. 11294-11303.

DOI : 10.1039/d2sc03592h

The mechanism of Fe induced bond stability of uranyl(v)

T. Vitova; R. Faizova; J. Amaro-Estrada; L. Maron; T. Pruessmann et al. 

Chemical Science

2022-08-05

Vol. 13 , num. 37, p. 11038-11047.

DOI : 10.1039/d2sc03416f

Cation assisted binding and cleavage of dinitrogen by uranium complexes

N. Jori; T. Rajeshkumar; R. Scopelliti; I. Zivkovic; A. Sienkiewicz et al. 

Chemical Science

2022-07-14

Vol. 13 , num. 32, p. 9232-9242.

DOI : 10.1039/d2sc02530b

Nitrogen activation and cleavage by a multimetallic uranium complex

M. Keener; F. Fadaei Tirani; R. Scopelliti; I. Zivkovic; M. Mazzanti 

Chemical Science

2022-07-13

Vol. 13 , num. 27, p. 8025-8035.

DOI : 10.1039/D2SC02997A

Design Principles for the Development of Gd(III) Polarizing Agents for Magic Angle Spinning Dynamic Nuclear Polarization

Y. Rao; C. T. Palumbo; A. Venkatesh; M. Keener; G. Stevanato et al. 

Journal Of Physical Chemistry C

2022-07-05

Vol. 126 , num. 27, p. 11310-11317.

DOI : 10.1021/acs.jpcc.2c01721

Structure and Reactivity of Polynuclear Divalent Lanthanide Disiloxanediolate Complexes br

A. R. Willauer; F. Fadaei-Tirani; I. Zivkovic; A. Sienkiewicz; M. Mazzanti 

Inorganic Chemistry

2022-05-16

Vol. 61 , num. 19, p. 7436-7447.

DOI : 10.1021/acs.inorgchem.2c00479

Multi-electron Transfer by U(II) and Masked U(II) Complexes

D. K. Modder; M. Mazzanti 

Chimia

2022-04-01

Vol. 76 , num. 4, p. 303-307.

DOI : 10.2533/chimia.2022.303

Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer

L. Barluzzi; N. Jori; L. Maron; R. Scopelliti; P. Oyala et al. 

Chemical Communications

2022-03-10

Vol. 58 , num. 29, p. 4655-4658.

DOI : 10.1039/D2CC00473A

Reactivity of Multimetallic Thorium Nitrides Generated by Reduction of Thorium Azides

F-C. Hsueh; L. Barluzzi; M. Keener; T. Rajeshkumar; L. Maron et al. 

Journal of the American Chemical Society

2022-02-09

Vol. 144 , num. 7, p. 3222-3232.

DOI : 10.1021/jacs.1c13150

Gd3+-Functionalized Lithium Niobate Nanoparticles for Dual Multiphoton and Magnetic Resonance Bioimaging

R. De Matos; A. Gheata; G. Campargue; J. Vuilleumier; L. Nicolle et al. 

ACS Applied Nano Materials

2022-02-03

Vol. 5 , num. 2, p. 2912-2922.

DOI : 10.1021/acsanm.2c00127

Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides

A. R. Willauer; I. Douair; A-S. Chauvin; F. Fadaei-Tirani; J-C. G. Bunzli et al. 

Chemical Science

2022-01-21

Vol. 13 , p. 681-691.

DOI : 10.1039/d1sc05517h

2021

Nitride protonation and NH3 binding versus N-H bond cleavage in uranium nitrides

M. Keener; R. Scopelliti; M. Mazzanti 

Chemical Science

2021-08-18

Vol. 12 , num. 38, p. 12610-12618.

DOI : 10.1039/d1sc03957a

Stepwise Reduction of Dinitrogen by a Uranium-Potassium Complex Yielding a U(VI)/U(IV) Tetranitride Cluster

N. Jori; L. Barluzzi; I. Douair; L. Maron; F. Fadaei-Tirani et al. 

Journal Of The American Chemical Society

2021-07-28

Vol. 143 , num. 29, p. 11225-11234.

DOI : 10.1021/jacs.1c05389

Synthesis, structure, and reactivity of uranium(VI) nitrides

L. Barluzzi; F-C. Hsueh; R. Scopelliti; B. E. Atkinson; N. Kaltsoyannis et al. 

Chemical Science

2021-04-30

Vol. 12 , num. 23, p. 8096-8104.

DOI : 10.1039/d1sc01796a

Single metal four-electron reduction by U(II) and masked “U(II)” compounds

D. K. Modder; C. T. Palumbo; I. Douair; R. Scopelliti; L. Maron et al. 

Chemical Science

2021-03-22

Vol. 12 , num. 17, p. 6153-6158.

DOI : 10.1039/d1sc00668a

Biological reduction of a U(V)-organic ligand complex

M. Molinas; R. Faizova; A. Brown; J. Galanzew; B. Schacherl et al. 

Environmental Science & Technology

2021-03-11

Vol. 55 , num. 8, p. 4753–4761.

DOI : 10.1021/acs.est.0c06633

Synthesis and Characterization of Water Stable Uranyl(V) Complexes

R. Faizova; F. Fadaei‐Tirani; A. Chauvin; M. Mazzanti 

Angewandte Chemie International Edition

2021-01-11

Vol. 60 , num. 15, p. 8227-8235.

DOI : 10.1002/anie.202016123

Delivery of a Masked Uranium(II) by an Oxide-Bridged Diuranium(III) Complex

D. K. Modder; C. T. Palumbo; I. Douair; F. Fadaei-Tirani; L. Maron et al. 

Angewandte Chemie-International Edition

2021

Vol. 60 , num. 7, p. 3737-3744.

DOI : 10.1002/anie.202013473

2020

Photochemical Synthesis of a Stable Terminal Uranium(VI) Nitride

L. Barluzzi; R. Scopelliti; M. Mazzanti 

Journal Of The American Chemical Society

2020-11-11

Vol. 142 , num. 45, p. 19047-19051.

DOI : 10.1021/jacs.0c09814

Carbon dioxide reduction by lanthanide(iii) complexes supported by redox-active Schiff base ligands

N. Jori; D. Toniolo; B. C. Huynh; R. Scopelliti; M. Mazzanti 

Inorganic Chemistry Frontiers

2020-10-07

Vol. 7 , num. 19, p. 3598-3608.

DOI : 10.1039/d0qi00801j

Structure and small molecule activation reactivity of a metallasilsesquioxane of divalent ytterbium

A. R. Willauer; A. M. Dabrowska; R. Scopelliti; M. Mazzanti 

Chemical Communications

2020-08-14

Vol. 56 , num. 63, p. 8936-8939.

DOI : 10.1039/d0cc04197a

Carbon Dioxide Reduction by Multimetallic Uranium(IV) Complexes Supported by Redox-Active Schiff Base Ligands

N. Jori; M. Falcone; R. Scopelliti; M. Mazzanti 

Organometallics

2020-05-11

Vol. 39 , num. 9, p. 1590-1601.

DOI : 10.1021/acs.organomet.9b00792

Assembly of High-Spin [Fe-3] Clusters by Ligand-Based Multielectron Reduction

D. Toniolo; R. Scopelliti; I. Zivkovic; M. Mazzanti 

Journal Of The American Chemical Society

2020-04-22

Vol. 142 , num. 16, p. 7301-7305.

DOI : 10.1021/jacs.0c01664

Accessing the plus IV Oxidation State in Molecular Complexes of Praseodymium

A. R. Willauer; C. T. Palumbo; F. Fadaei-Tirani; I. Zivkovic; I. Douair et al. 

Journal Of The American Chemical Society

2020-03-25

Vol. 142 , num. 12, p. 5538-5542.

DOI : 10.1021/jacs.0c01204

Ligand-Supported Facile Conversion of Uranyl(VI) into Uranium(IV) in Organic and Aqueous Media

R. Faizova; F. Fadaei-Tirani; R. Bernier-Latmani; M. Mazzanti 

Angewandte Chemie-International Edition

2020-02-28

Vol. 59 , num. 17, p. 6756-6759.

DOI : 10.1002/anie.201916334

C-H Bond Activation by an Isolated Dinuclear U(III)/U(IV) Nitride

C. T. Palumbo; R. Scopelliti; I. Zivkovic; M. Mazzanti 

Journal Of The American Chemical Society

2020-02-12

Vol. 142 , num. 6, p. 3149-3157.

DOI : 10.1021/jacs.9b12804

Anhydrous Conditions Enable the Catalyst-Free Carboxylation of Aromatic Alkynes with CO2 under Mild Conditions

D. Toniolo; F. D. Bobbink; P. J. Dyson; M. Mazzanti 

Helvetica Chimica Acta

2020-01-27

Vol. 103 , num. 2, p. e1900258.

DOI : 10.1002/hlca.201900258

Stabilization of the Oxidation State plus IV in Siloxide-Supported Terbium Compounds

A. R. Willauer; C. T. Palumbo; R. Scopelliti; I. Zivkovic; I. Douair et al. 

Angewandte Chemie-International Edition

2020-01-23

Vol. 59 , num. 9, p. 3549-3553.

DOI : 10.1002/anie.201914733

Synthesis, reactivity, and environmental relevance of uranyl(V) complexes.

R. Faizova / Director(s) : M. Mazzanti 

Lausanne: EPFL

2020

p. 261.

DOI : 10.5075/epfl-thesis-8235

Activation of small molecules promoted by multimetallic complexes supported by redox active ligands

D. Toniolo / Director(s) : M. Mazzanti 

Lausanne: EPFL

2020

p. 278.

DOI : 10.5075/epfl-thesis-10337

2019

Small molecule activation by multimetallic uranium complexes supported by siloxide ligands

L. Barluzzi; M. Falcone; M. Mazzanti 

Chemical Communications

2019-11-11

Vol. 55 , num. 87, p. 13031-13047.

DOI : 10.1039/c9cc05605j

Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands

C. T. Palumbo; L. Barluzzi; R. Scopelliti; I. Zivkovic; A. Fabrizio et al. 

Chemical Science

2019-10-14

Vol. 10 , num. 38, p. 8840-8849.

DOI : 10.1039/c9sc02149c

Uncovering unprecedented uranium species: From water-stable uranyl(V) to U(IV) POM clusters

R. Faizova; L. Chatelain; R. Scopelliti; M. Mazzanti 

Abstracts Of Papers Of The American Chemical Society

2019-08-25

Fall National Meeting and Exposition of the American-Chemical-Society (ACS), San Diego, CA, Aug 25-29, 2019.

Tuning reactivity of nitride bridged uranium complexes with amide and siloxide ligands

C. Palumbo; L. Barluzzi; R. Scopelliti; M. Mazzanti 

Abstracts Of Papers Of The American Chemical Society

2019-08-25

Fall National Meeting and Exposition of the American-Chemical-Society (ACS), San Diego, CA, Aug 25-29, 2019.

Theoretical Investigation of the Electronic Structure and Magnetic Properties of Oxo-Bridged Uranyl(V) Dinuclear and Trinuclear Complexes

B. Teyar; S. Boucenina; L. Belkhiri; B. Le Guennic; A. Boucekkine et al. 

Inorganic Chemistry

2019-08-05

Vol. 58 , num. 15, p. 10097-10110.

DOI : 10.1021/acs.inorgchem.9b01237

Molecular Complex of Tb in the +4 Oxidation State

C. T. Palumbo; I. Zivkovic; R. Scopelliti; M. Mazzanti 

Journal Of The American Chemical Society

2019-06-26

Vol. 141 , num. 25, p. 9827-9831.

DOI : 10.1021/jacs.9b05337

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride

M. Falcone; R. Scopelliti; M. Mazzanti 

Journal Of The American Chemical Society

2019-06-19

Vol. 141 , num. 24, p. 9570-9577.

DOI : 10.1021/jacs.9b02235

A Factor Two Improvement in High-Field Dynamic Nuclear Polarization from Gd(III) Complexes by Design

G. Stevanato; D. J. Kubicki; G. Menzildjian; A-S. Chauvin; K. Keller et al. 

Journal Of The American Chemical Society

2019-06-05

Vol. 141 , num. 22, p. 8746-8751.

DOI : 10.1021/jacs.9b03723

publication thumbnail

CS2 Reductive Coupling to Acetylenedithiolate by a Dinuclear Ytterbium(II) Complex

M. Mazzanti; D. Toniolo; A. R. Willauer; R. Scopelliti; J. Andrez et al. 

Chemistry – A European Journal

2019-04-08

Vol. 25 , num. 33, p. 7831-7834.

DOI : 10.1002/chem.201901321

Recent developments in uranium(V) chemistry

M. Mazzanti 

Abstracts Of Papers Of The American Chemical Society

2019-03-31

National Meeting of the American-Chemical-Society (ACS), Orlando, FL, Mar 31-Apr 04, 2019.

Correction: Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex (vol 10, pg 3543, 2019)

L. Barluzzi; L. Chatelain; F. Fadaei-Tirani; I. Zivkovic; M. Mazzanti 

Chemical Science

2019-03-28

Vol. 10 , num. 12, p. 3687-3687.

DOI : 10.1039/c9sc90049g

publication thumbnail

A complete series of uranium(iv) complexes with terminal hydrochalcogenido (EH) and chalcogenido (E) ligands E = O, S, Se, Te

M. W. Rosenzweig; J. Hümmer; A. Scheurer; C. A. Lamsfus; F. W. Heinemann et al. 

Dalton Transactions

2019-03-25

Vol. 48 , num. 29, p. 10853-10864.

DOI : 10.1039/C9DT00530G

publication thumbnail

Carbon dioxide reduction by dinuclear Yb(ii) and Sm(ii) complexes supported by siloxide ligands

A. R. Willauer; D. Toniolo; F. Fadaei-Tirani; Y. Yang; M. Laurent et al. 

Dalton Transactions

2019-03-14

Vol. 48 , num. 18, p. 6100-6110.

DOI : 10.1039/C9DT00554D

publication thumbnail

Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex

L. Barluzzi; L. Chatelain; F. Fadaei-Tirani; I. Zivkovic; M. Mazzanti 

Chemical Science

2019-02-18

Vol. 10 , num. 12, p. 3543-3555.

DOI : 10.1039/C8SC05721D

publication thumbnail

Structural Snapshots of Cluster Growth from {U6 } to {U38 } During the Hydrolysis of UCl4

L. Chatelain; R. Faizova; F. Fadaei-Tirani; J. Pécaut; M. Mazzanti 

Angewandte Chemie International Edition

2019-01-02

Vol. 58 , num. 10, p. 3021-3026.

DOI : 10.1002/anie.201812509

Small Molecule Activation by Multimetallic Uranium Complexes

M. Falcone / Director(s) : M. Mazzanti 

Lausanne: EPFL

2019

p. 334.

DOI : 10.5075/epfl-thesis-9539

publication thumbnail

The role of bridging ligands in dinitrogen reduction and functionalization by uranium multimetallic complexes

M. Falcone; L. Barluzzi; J. Andrez; F. Fadaei Tirani; I. Zivkovic et al. 

Nature Chemistry

2019

Vol. 11 , p. 154-160.

DOI : 10.1038/s41557-018-0167-8

2018

publication thumbnail

Synthesis and Characterization of a Water Stable Uranyl(V) Complex

R. Faizova; R. Scopelliti; A-S. Chauvin; M. Mazzanti 

Journal of the American Chemical Society

2018-10-05

Vol. 140 , num. 42, p. 13554-13557.

DOI : 10.1021/jacs.8b07885

publication thumbnail

The effect of iron binding on uranyl(V) stability

R. Faizova; R. Scopelliti; M. Mazzanti; S. White 

Chemical Science

2018-08-14

num. 2018, 9, p. 7520-7527.

DOI : 10.1039/C8SC02099J

publication thumbnail

A tetranuclear samarium(II) inverse sandwich from direct reduction of toluene by a samarium(II) siloxide

R. P. Kelly; D. Toniolo; F. Fadaei Tirani; L. Maron; M. Mazzanti 

ChemCom

2018-08-09

num. 73, 2018, p. 10268-10271.

DOI : 10.1039/C8CC04169E

Four-electron Reduction and Functionalization of N₂ by a Uranium(III) Bridging Nitride

M. Falcone; M. Mazzanti 

Chimia

2018-04-25

Vol. 72 , num. 4, p. 199-202.

DOI : 10.2533/chimia.2018.199

Reversible Dihydrogen Activation and Hydride Transfer by a Uranium Nitride Complex

M. Falcone; L. N. Poon; F. Fadaei Tirani; M. Mazzanti 

Angewandte Chemie International Edition

2018-03-27

Vol. 57 , num. 14, p. 3697-3700.

DOI : 10.1002/anie.201800203

The secret is in the ring

M. Mazzanti 

NATURE CHEMISTRY

2018

Vol. 10 , num. 3, p. 247-249.

DOI : 10.1038/nchem.2940

Synthesis and reactivity of complexes of f elements supported by siloxide ligands

M. Mazzanti 

Abstracts Of Papers Of The American Chemical Society

2018

p. 255

2017

Reduction of a Cerium(III) Siloxide Complex To Afford a Quadruple-Decker Arene-Bridged Cerium(II) Sandwich

R. P. Kelly; L. Maron; R. Scopelliti; M. Mazzanti 

Angewandte Chemie-International Edition

2017

Vol. 56 , num. 49, p. 15663-15666.

DOI : 10.1002/anie.201709769

publication thumbnail

A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand framework

C. Camp; D. Toniolo; J. Andrez; J. Pécaut; M. Mazzanti 

Dalton Transactions

2017

Vol. 46 , num. 34, p. 11145-11148.

DOI : 10.1039/C7DT01993A

publication thumbnail

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

R. P. Kelly; M. Falcone; C. A. Lamsfus; R. Scopelliti; L. Maron et al. 

Chemical Science

2017

Vol. 8 , num. 8, p. 5319-5328.

DOI : 10.1039/C7SC01111C

publication thumbnail

Nitrogen reduction and functionalization by a multimetallic uranium nitride complex

M. Falcone; L. Chatelain; R. Scopelliti; I. Živković; M. Mazzanti 

Nature

2017

Vol. 547 , num. 7663, p. 332-335.

DOI : 10.1038/nature23279

publication thumbnail

Ligand and Metal Based Multielectron Redox Chemistry of Cobalt Supported by Tetradentate Schiff Bases

J. Andrez; V. Guidal; R. Scopelliti; J. Pécaut; S. Gambarelli et al. 

Journal of the American Chemical Society

2017

Vol. 139 , num. 25, p. 8628-8638.

DOI : 10.1021/jacs.7b03604

CO Cleavage and CO2 Functionalization under Mild Conditions by a Multimetallic CsU2 Nitride Complex

M. Falcone; L. Chatelain; R. Scopelliti; M. Mazzanti 

Chimia

2017

Vol. 71 , num. 4, p. 209-212.

DOI : 10.2533/chimia.2017.209

publication thumbnail

Synthesis and SMM behaviour of trinuclear versus dinuclear 3d-5f uranyl(v)-cobalt(II) cation-cation complexes

L. Chatelain; F. Tuna; J. Pecaut; M. Mazzanti 

Dalton Transactions

2017

Vol. 46 , num. 17, p. 5498-5502.

DOI : 10.1039/c6dt04558h

2016

Isolation of a Star-Shaped Uranium(V/VI) Cluster from the Anaerobic Photochemical Reduction of Uranyl(VI)

L. Chatelain; S. White; R. Scopelliti; M. Mazzanti 

Angewandte Chemie-International Edition

2016

Vol. 55 , num. 46, p. 14323-14327.

DOI : 10.1002/anie.201608754

Facile CO Cleavage by a Multimetallic CsU2 Nitride Complex

M. Falcone; C. E. Kefalidis; R. Scopelliti; L. Maron; M. Mazzanti 

Angewandte Chemie International Edition

2016

Vol. 55 , num. 40, p. 12290-12294.

DOI : 10.1002/anie.201606796

Enhancement of silicon solar cells by downshifting with Eu and Tb coordination complexes

T. Fix; A. Nonat; D. Imbert; S. Di Pietro; M. Mazzanti et al. 

Progress in Photovoltaics: Research and Applications

2016

Vol. 24 , num. 9, p. 1251-1260.

DOI : 10.1002/pip.2785

Uranium(IV) Terminal Hydrosulfido and Sulfido Complexes: The Nature of the Uranium–Sulfur Bond

M. W. Rosenzweig; A. Scheurer; F. Heinemann; C. Alvarez Lamsfus; L. Maron et al. 

Chem. Sci.

2016

Vol. 7 , num. 9, p. 5857-5866.

DOI : 10.1039/C6SC00677A

Synthesis and reactivity of a terminal uranium(IV) sulfide supported by siloxide ligands

M. Mazzanti; J. Andrez; J. Pecaut; R. Scopelliti; L. Maron et al. 

Chem. Sci.

2016

Vol. 7 , num. 9, p. 5846-5856.

DOI : 10.1039/C6SC00675B

Sensitisation of visible and NIR lanthanide emission by InPZnS quantum dots in bi-luminescent hybrids

J. K. Molloy; C. Lincheneau; M. M. Karimdjy; F. Agnese; L. Mattera et al. 

Chemical Communications

2016

Vol. 52 , num. 24, p. 4577-4580.

DOI : 10.1039/C6CC01182A

Versatile pyridine-2,6-bis-tetrazolate scaffolds for the formation of highly luminescent lanthanide complexes

S. Di Pietro; N. Gautier; D. Imbert; J. Pécaut; M. Mazzanti 

Dalton Transactions

2016

Vol. 45 , num. 8, p. 3429-3442.

DOI : 10.1039/C5DT04811G

Nucleophilic Reactivity of a Nitride-Bridged Diuranium(IV) Complex: CO2 and CS2 Functionalization

M. Falcone; L. Chatelain; M. Mazzanti 

Angewandte Chemie International Edition

2016

Vol. 55 , num. 12, p. 4074-4078.

DOI : 10.1002/anie.201600158

Synthesis and Structure of Nitride-Bridged Uranium(III) Complexes

L. Chatelain; R. Scopelliti; M. Mazzanti 

Journal of the American Chemical Society

2016

Vol. 138 , num. 6, p. 1784-1787.

DOI : 10.1021/jacs.5b12620

2015

Heterometallic Fe-2(II)-U-V and Ni-2(II)-U-V Exchange-Coupled Single-Molecule Magnets: Effect of the 3d Ion on the Magnetic Properties

L. Chatelain; J. Pecaut; F. Tuna; M. Mazzanti 

Chemistry-A European Journal

2015

Vol. 21 , num. 50, p. 18038-18042.

DOI : 10.1002/chem.201503637

CO2 conversion to isocyanate via multiple N–Si bond cleavage at a bulky uranium(III) complex

C. Camp; L. Chatelain; C. E. Kefalidis; J. Pécaut; L. Maron et al. 

Chemical Communications

2015

num. 51, p. 15454-15457.

DOI : 10.1039/C5CC06707C

A zig-zag uranyl(V)- Mn(II) single chain magnet with a high relaxation barrier

L. Chatelain; F. Tuna; J. Pécaut; M. Mazzanti 

Chemical Communications

2015

Vol. 51 , num. 56, p. 11309-11312.

DOI : 10.1039/C5CC02945G

Lanthanide(II) Complexes Supported by N,O-Donor Tripodal Ligands: Synthesis, Structure, and Ligand-Dependent Redox Behavior

J. Andrez; G. Bozoklu; G. Nocton; J. Pécaut; R. Scopelliti et al. 

Chemistry – A European Journal

2015

Vol. 21 , p. 15188-15200.

DOI : 10.1002/chem.201502204

Ferrocene-Based Tetradentate Schiff Bases as Supporting Ligands in Uranium Chemistry

C. Camp; L. Chatelain; V. Mougel; J. Pécaut; M. Mazzanti 

Inorganic Chemistry

2015

Vol. 54 , num. 12, p. 5774-5783.

DOI : 10.1021/acs.inorgchem.5b00467

Confinement of a tris-aqua Gd(III) complex in silica nanoparticles leads to high stability and high relaxivity and supresses anion binding

M. M. Karimdjy; G. Tallec; P. H. Fries; D. Imbert; M. Mazzanti 

Chemical Communications

2015

Vol. 51 , num. 31, p. 6836-6838.

DOI : 10.1039/c5cc01352f

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

C. Camp; O. Cooper; J. Andrez; J. Pecaut; M. Mazzanti 

Dalton Transactions

2015

Vol. 44 , num. 6, p. 2650-2656.

DOI : 10.1039/c4dt02585g

2014

Single-Molecule-Magnet Behavior in Mononuclear Homoleptic Tetrahedral Uranium(III) Complexes

L. C. J. Pereira; C. Camp; J. T. Coutinho; L. Chatelain; P. Maldivi et al. 

Inorganic Chemistry

2014

Vol. 53 , num. 22, p. 11809-11811.

DOI : 10.1021/ic501520c

Self-Assembly of a 3d-5f Trinuclear Single-Molecule Magnet from a Pentavalent Uranyl Complex

L. Chatelain; J. P. S. Walsh; J. Pecaut; F. Tuna; M. Mazzanti 

Angewandte Chemie-International Edition

2014

Vol. 53 , num. 49, p. 13434-13438.

DOI : 10.1002/anie.201407334

A Uranium-Based UO2+-Mn2+ Single-Chain Magnet Assembled trough Cation-Cation Interactions

V. Mougel; L. Chatelain; J. Hermle; R. Caciuffo; E. Colineau et al. 

Angewandte Chemie-International Edition

2014

Vol. 53 , num. 3, p. 819-823.

DOI : 10.1002/anie.201307366

Gadolinium Complexes Confined in Silica Nanoparticles as a Highly Efficient MRI Contrast Agents

M. M. Karimdjy; P. Fries; D. Imbert; M. Mazzanti; N. Wartenberg et al. 

Journal of Biological Inorganic Chemistry

2014

Vol. 19 , p. S451-S451.

An efficient triazole-pyridine-bistetrazolate platform for highly luminescent lanthanide complexes

S. Di Pietro; D. Imbert; M. Mazzanti 

Chemical Communications

2014

Vol. 50 , num. 71, p. 10323-10326.

DOI : 10.1039/c4cc04060k

Multimetallic Cooperativity in Uranium-Mediated CO2 Activation

O. Cooper; C. Camp; J. Pecaut; C. E. Kefalidis; L. Maron et al. 

Journal of the American Chemical Society

2014

Vol. 136 , num. 18, p. 6716-6723.

DOI : 10.1021/ja5017624

Two-electron versus one-electron reduction of chalcogens by uranium(III): synthesis of a terminal U(V) persulfide complex

C. Camp; M. A. Antunes; G. Garcia; I. Ciofini; I. C. Santos et al. 

Chemical Science

2014

Vol. 5 , num. 2, p. 841-846.

DOI : 10.1039/c3sc52742e

Tuning Lanthanide Reactivity Towards Small Molecules with Electron-Rich Siloxide Ligands

J. Andrez; J. Pecaut; P-A. Bayle; M. Mazzanti 

Angewandte Chemie-International Edition

2014

Vol. 53 , num. 39, p. 10448-10452.

DOI : 10.1002/anie.201405031

2013

Luminescent latex particles loaded with anionic lanthanide complexes: a versatile platform for multicolour optical coding

N. Wartenberg; O. Raccurt; D. Imbert; M. Mazzanti; E. Bourgeat-Lami 

Journal of Materials Chemistry C

2013

Vol. 1 , num. 10, p. 2061-2068.

DOI : 10.1039/c3tc00756a

Multicolour Optical Coding from a Series of Luminescent Lanthanide Complexes with a Unique Antenna

N. Wartenberg; O. Raccurt; E. Bourgeat-Lami; D. Imbert; M. Mazzanti 

Chemistry-a European Journal

2013

Vol. 19 , num. 10, p. 3477-3482.

DOI : 10.1002/chem.201203657

Radioactive Europium-Chelate-Based Silica Nanoparticles as a Probe for Stability, Incorporation Efficiency and Trace Analysis

N. Wartenberg; O. Raccurt; E. Bourgeat-Lami; D. Imbert; M. Mazzanti 

European Journal of Inorganic Chemistry

2013

num. 9, p. 1493-1498.

DOI : 10.1002/ejic.201201189

A Gadolinium Complex Confined in Silica Nanoparticles as a Highly Efficient T1/T2 MRI Contrast Agent

N. Wartenberg; P. Fries; O. Raccurt; A. Guillermo; D. Imbert et al. 

Chemistry-a European Journal

2013

Vol. 19 , num. 22, p. 6980-6983.

DOI : 10.1002/chem.201300635

Optimizing the relaxivity of Gd(III) complexes appended to InP/ZnS quantum dots by linker tuning

G. J. Stasiuk; S. Tamang; D. Imbert; C. Gateau; P. Reiss et al. 

Dalton Transactions

2013

Vol. 42 , num. 23, p. 8197-8200.

DOI : 10.1039/c3dt50774b

Diamine Bis(phenolate) as Supporting Ligands in Organoactinide(IV) Chemistry. Synthesis, Structural Characterization, and Reactivity of Stable Dialkyl Derivatives

E. Mora; L. Maria; B. Biswas; C. Camp; I. C. Santos et al. 

Organometallics

2013

Vol. 32 , num. 5, p. 1409-1422.

DOI : 10.1021/om3010806

Efficient sensitization of Ln(3+)-doped NaYF4 nanocrystals with organic ligands

N. Gauthier; O. Raccurt; D. Imbert; M. Mazzanti 

Journal of Nanoparticle Research

2013

Vol. 15 , num. 6, p. 1723.

DOI : 10.1007/s11051-013-1723-1

Tuning Uranium-Nitrogen Multiple Bond Formation with Ancillary Siloxide Ligands

C. Camp; J. Pecaut; M. Mazzanti 

Journal of the American Chemical Society

2013

Vol. 135 , num. 32, p. 12101-12111.

DOI : 10.1021/ja405815b

Controlled Thermolysis of Uranium (Alkoxy) siloxy Complexes: A Route to Polymetallic Complexes of Low-Valent Uranium

C. Camp; C. E. Kefalidis; J. Pecaut; L. Maron; M. Mazzanti 

Angewandte Chemie-International Edition

2013

Vol. 52 , num. 48, p. 12646-12650.

DOI : 10.1002/anie.201307291

Synthesis of Electron-Rich Uranium(IV) Complexes Supported by Tridentate Schiff Base Ligands and Their Multi-Electron Redox Chemistry

C. Camp; J. Andrez; J. Pecaut; M. Mazzanti 

Inorganic Chemistry

2013

Vol. 52 , num. 12, p. 7078-7086.

DOI : 10.1021/ic4006218

Crystal structure diversity in the bis hydrotris-(3,5-dimethylpyrazolyl)borate iodouranium(III) complex: from neutral to cationic forms

M. A. Antunes; I. C. Santos; H. Bolvin; L. C. J. Pereira; M. Mazzanti et al. 

Dalton Transactions

2013

Vol. 42 , num. 24, p. 8861-8867.

DOI : 10.1039/c3dt50753j

Lanthanide Complexes Based on beta-Diketonates and a Tetradentate Chromophore Highly Luminescent as Powders and in Polymers

E. S. Andreiadis; N. Gauthier; D. Imbert; R. Demadrille; J. Pecaut et al. 

Inorganic Chemistry

2013

Vol. 52 , num. 24, p. 14382-14390.

DOI : 10.1021/ic402523v

2012

New polynuclear U(IV)-U(V) complexes from U(IV) mediated uranyl(V) disproportionation

V. Mougel; J. Pecaut; M. Mazzanti 

Chemical Communications

2012

Vol. 48 , num. 6, p. 868-870.

DOI : 10.1039/c1cc16646h

Uranium and manganese assembled in a wheel-shaped nanoscale single-molecule magnet with high spin-reversal barrier

V. Mougel; L. Chatelain; J. Pecaut; R. Caciuffo; E. Colineau et al. 

Nature Chemistry

2012

Vol. 4 , num. 12, p. 1011-1017.

DOI : 10.1038/nchem.1494

Siloxides as Supporting Ligands in Uranium(III)-Mediated Small-Molecule Activation

V. Mougel; C. Camp; J. Pecaut; C. Coperet; L. Maron et al. 

Angewandte Chemie-International Edition

2012

Vol. 51 , num. 49, p. 12280-12284.

DOI : 10.1002/anie.201206955

Single-ion magnet behaviour in U(Tp(Me2))(2)I

J. T. Coutinho; M. A. Antunes; L. C. J. Pereira; H. Bolvin; J. Marcalo et al. 

Dalton Transactions

2012

Vol. 41 , num. 44, p. 13568-13571.

DOI : 10.1039/c2dt31421e

A tetrameric neptunyl(v) cluster supported by a Schiff base ligand

R. Copping; V. Mougel; C. Den Auwer; C. Berthon; P. Moisy et al. 

Dalton Transactions

2012

Vol. 41 , num. 36, p. 10900-10902.

DOI : 10.1039/c2dt31072d

Magnetic communication and reactivity of a stable homometallic cation-cation trimer of pentavalent uranyl

L. Chatelain; V. Mougel; J. Pecaut; M. Mazzanti 

Chemical Science

2012

Vol. 3 , num. 4, p. 1075-1079.

DOI : 10.1039/c2sc00782g

Multielectron redox chemistry of lanthanide Schiff-base complexes

C. Camp; V. Guidal; B. Biswas; J. Pecaut; L. Dubois et al. 

Chemical Science

2012

Vol. 3 , num. 8, p. 2433-2448.

DOI : 10.1039/c2sc20476b

Metal-Controlled Diastereoselective Self-Assembly and Circularly Polarized Luminescence of a Chiral Heptanuclear Europium Wheel

G. Bozoklu; C. Gateau; D. Imbert; J. Pecaut; K. Robeyns et al. 

Journal of the American Chemical Society

2012

Vol. 134 , num. 20, p. 8372-8375.

DOI : 10.1021/ja3020814

Self-assembly of highly luminescent lanthanide complexes promoted by pyridine-tetrazolate ligands

E. S. Andreiadis; D. Imbert; J. Pecaut; R. Demadrille; M. Mazzanti 

Dalton Transactions

2012

Vol. 41 , num. 4, p. 1268-1277.

DOI : 10.1039/c1dt11627d

Highly relaxing gadolinium based MRI contrast agents responsive to Mg2+ sensing

S. Abada; A. Lecointre; M. Elhabiri; D. Esteban-Gomez; C. Platas-Iglesias et al. 

Chemical Communications

2012

Vol. 48 , num. 34, p. 4085-4087.

DOI : 10.1039/c2cc30757j

New Bisaqua Picolinate-Based Gadolinium Complexes as MRI Contrast Agents with Substantial High-Field Relaxivities

A. M. Nonat; C. Gateau; P. H. Fries; L. Helm; M. Mazzanti 

European Journal Of Inorganic Chemistry

2012

p. 2049-2061.

DOI : 10.1002/ejic.201101162

2011

High Relaxivity and Stability of a Hydroxyquinolinate-Based Tripodal Monoaquagadolinium Complex for Use as a Bimodal MRI/Optical Imaging Agent

G. Tallec; P. H. Fries; D. Imbert; M. Mazzanti 

Inorganic Chemistry

2011

Vol. 50 , num. 17, p. 7943-7945.

DOI : 10.1021/ic2012793

Cell-Permeable Ln(III) Chelate-Functionalized InP Quantum Dots As Multimodal Imaging Agents

G. J. Stasiuk; S. Tamang; D. Imbert; C. Poillot; M. Giardiello et al. 

Acs Nano

2011

Vol. 5 , num. 10, p. 8193-8201.

DOI : 10.1021/nn202839w

MOLECULAR MAGNETISM: Uranium memory

M. Mazzanti 

Nature Chemistry

2011

Vol. 3 , num. 6, p. 426-427.

DOI : 10.1038/nchem.1057

A versatile precursor for non-aqueous neptunyl(V) chemistry

R. Copping; V. Mougel; S. Petit; C. Den Auwer; P. Moisy et al. 

Chemical Communications

2011

Vol. 47 , num. 19, p. 5497-5499.

DOI : 10.1039/c1cc11010a

Base-Driven Assembly of Large Uranium Oxo/Hydroxo Clusters

B. Biswas; V. Mougel; J. Pecaut; M. Mazzanti 

Angewandte Chemie-International Edition

2011

Vol. 50 , num. 25, p. 5744-5747.

DOI : 10.1002/anie.201101327

U(Tp(Me2))(2)(bipy) (+): A Cationic Uranium(III) Complex with Single-Molecule-Magnet Behavior

M. A. Antunes; L. C. J. Pereira; I. C. Santos; M. Mazzanti; J. Marcalo et al. 

Inorganic Chemistry

2011

Vol. 50 , num. 20, p. 9915-9917.

DOI : 10.1021/ic200705p

Phosphorescent Binuclear Iridium Complexes Based on Terpyridine-Carboxylate: An Experimental and Theoretical Study

E. S. Andreiadis; D. Imbert; J. Pecaut; A. Calborean; I. Ciofini et al. 

Inorganic Chemistry

2011

Vol. 50 , num. 17, p. 8197-8206.

DOI : 10.1021/ic200704s

2010

Modulation of the unpaired spin localization in Pentavalent Uranyl Complexes

V. Vetere; P. Maldivi; M. Mazzanti 

Comptes Rendus Chimie

2010

Vol. 13 , num. 6-7, p. 876-883.

DOI : 10.1016/j.crci.2010.04.011

Highly stable and soluble bis-aqua Gd, Nd, Yb complexes as potential bimodal MRI/NIR imaging agents

G. Tallec; D. Imbert; P. H. Fries; M. Mazzanti 

Dalton Transactions

2010

Vol. 39 , num. 40, p. 9490-9492.

DOI : 10.1039/c0dt00994f

Lanthanide-chelate silica nanospheres as robust multicolor Vis-NIR tags

J. Samuel; G. Tallec; P. Cherns; W. L. Ling; O. Raccurt et al. 

Chemical Communications

2010

Vol. 46 , num. 15, p. 2647-2649.

DOI : 10.1039/b926031e

Ligand assisted cleavage of uranium oxo-clusters

G. Nocton; J. Pecaut; Y. Filinchuk; M. Mazzanti 

Chemical Communications

2010

Vol. 46 , num. 16, p. 2757-2759.

DOI : 10.1039/b926580e

Synthesis, Structure, and Bonding of Stable Complexes of Pentavalent Uranyl

G. Nocton; P. Horeglad; V. Vetere; J. Pecaut; L. Dubois et al. 

Journal of the American Chemical Society

2010

Vol. 132 , num. 2, p. 495-508.

DOI : 10.1021/ja9037164

Cation-Cation Complexes of Pentavalent Uranyl: From Disproportionation Intermediates to Stable Clusters

V. Mougel; P. Horeglad; G. Nocton; J. Pecaut; M. Mazzanti 

Chemistry-a European Journal

2010

Vol. 16 , num. 48, p. 14365-14377.

DOI : 10.1002/chem.201001929

New insights into the acid mediated disproportionation of pentavalent uranyl

V. Mougel; B. Biswas; J. Pecaut; M. Mazzanti 

Chemical Communications

2010

Vol. 46 , num. 45, p. 8648-8650.

DOI : 10.1039/c0cc03443f

Multielectron Redox Reactions Involving C-C Coupling and Cleavage in Uranium Schiff Base Complexes

C. Camp; V. Mougel; P. Horeglad; J. Pecaut; M. Mazzanti 

Journal of the American Chemical Society

2010

Vol. 132 , num. 49, p. 17374-17377.

DOI : 10.1021/ja1089364

Structural and photophysical properties of trianionic nine-coordinated near-IR emitting 8-hydroxyquinoline-based complexes

G. Bozoklu; C. Marchal; J. Pecaut; D. Imbert; M. Mazzanti 

Dalton Transactions

2010

Vol. 39 , num. 38, p. 9112-9122.

DOI : 10.1039/c0dt00225a

Diastereoselective Self-Assembly of a Homochiral Europium Triangle from a Bipyoxazoline-Carboxylate Ligand

G. Bozoklu; C. Marchal; C. Gateau; J. Pecaut; D. Imbert et al. 

Chemistry-a European Journal

2010

Vol. 16 , num. 21, p. 6159-6163.

DOI : 10.1002/chem.201000572

2009

Structural and Photophysical Studies of Highly Stable Lanthanide Complexes of Tripodal 8-Hydroxyquinolinate Ligands Based on 1,4,7-Triazacyclononane

A. Nonat; D. Imbert; J. Pecaut; M. Giraud; M. Mazzanti 

Inorganic Chemistry

2009

Vol. 48 , num. 9, p. 4207-4218.

DOI : 10.1021/ic9000076

Water Stability and Luminescence of Lanthanide Complexes of Tripodal Ligands Derived from 1,4,7-Triazacyclononane: Pyridinecarboxamide versus Pyridinecarboxylate Donors

G. Nocton; A. Nonat; C. Gateau; M. Mazzanti 

Helvetica Chimica Acta

2009

Vol. 92 , num. 11, p. 2257-2273.

DOI : 10.1002/hlca.200900150

Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed-Valent Uranyl Complex by Cation-Cation Interactions

V. Mougel; P. Horeglad; G. Nocton; J. Pecaut; M. Mazzanti 

Angewandte Chemie-International Edition

2009

Vol. 48 , num. 45, p. 8477-8480.

DOI : 10.1002/anie.200903457

Lanthanide-Based Coordination Polymers Assembled by a Flexible Multidentate Linker: Design, Structure, Photophysical Properties, and Dynamic Solid-State Behavior

C. Marchal; Y. Filinchuk; X-Y. Chen; D. Imbert; M. Mazzanti 

Chemistry-a European Journal

2009

Vol. 15 , num. 21, p. 5273-5288.

DOI : 10.1002/chem.200802589

Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

P. Horeglad; G. Nocton; Y. Filinchuk; J. Pecaut; M. Mazzanti 

Chemical Communications

2009

num. 14, p. 1843-1845.

DOI : 10.1039/b821398d

Remarkable Tuning of the Coordination and Photophysical Properties of Lanthanide Ions in a Series of Tetrazole-Based Complexes

E. S. Andreiadis; R. Demadrille; D. Imbert; J. Pecaut; M. Mazzanti 

Chemistry-a European Journal

2009

Vol. 15 , num. 37, p. 9458-9476.

DOI : 10.1002/chem.200900912

Gadolinium(III) complexes of 1,4,7-triazacyclononane based picolinate ligands: simultaneous optimization of water exchange kinetics and electronic relaxation

A. Nonat; M. Giraud; C. Gateau; P. H. Fries; L. Helm et al. 

Dalton Transactions

2009

p. 8033-8046.

DOI : 10.1039/b907738c

2008

A nitrido-centered uranium azido cluster obtained from a uranium azide

G. Nocton; J. Pecaut; M. Mazzanti 

Angewandte Chemie-International Edition

2008

Vol. 47 , num. 16, p. 3040-3042.

DOI : 10.1002/anie.200705742

Polynuclear Cation-Cation Complexes of Pentavalent Uranyl: Relating Stability and Magnetic Properties to Structure

G. Nocton; P. Horeglad; J. Pecaut; M. Mazzanti 

Journal of the American Chemical Society

2008

Vol. 130 , num. 49, p. 16633-16645.

DOI : 10.1021/ja804766r

Efficient sensitization of lanthanide luminescence by tetrazole-based polydentate ligands

M. Giraud; E. S. Andreiadis; A. S. Fisyuk; R. Demadrille; J. Pecaut et al. 

Inorganic Chemistry

2008

Vol. 47 , num. 10, p. 3952-3954.

DOI : 10.1021/ic8005663

A flexible tripodal ligand linking octametallic terbium rings into luminescent polymeric chains

X-Y. Chen; C. Marchal; Y. Filinchuk; D. Imbert; M. Mazzanti 

Chemical Communications

2008

num. 29, p. 3378-3380.

DOI : 10.1039/b803505a

2007

Relating structural and thermodynamic effects of the Pb(II) lone pair: A new picolinate ligand designed to accommodate the Pb(II) lone pair leads to high stability and selectivity

A. Pellissier; Y. Bretonniere; N. Chatterton; J. Pecaut; P. Delangle et al. 

Inorganic Chemistry

2007

Vol. 46 , num. 9, p. 3714-3725.

DOI : 10.1021/ic061823d

Structure, stability, dynamics, high-field relaxivity and ternary-complex formation of a new tris(aquo) gadolinium complex

A. Nonat; P. H. Fries; J. Pecaut; M. Mazzanti 

Chemistry-a European Journal

2007

Vol. 13 , num. 30, p. 8489-8506.

DOI : 10.1002/chem.200601856

Self-assembly of polyoxo clusters and extended frameworks by controlled hydrolysis of low-valent uranium

G. Nocton; F. Burdet; J. Pecaut; M. Mazzanti 

Angewandte Chemie-International Edition

2007

Vol. 46 , num. 40, p. 7574-7578.

DOI : 10.1002/anie.200702374

A comparative spectroscopic study of U(III)/Am(III) and Ln(III) complexed with N-donor ligands

M. A. Denecke; P. J. Panak; F. Burdet; M. Weigl; A. Geist et al. 

Comptes Rendus Chimie

2007

Vol. 10 , num. 10-11, p. 872-882.

DOI : 10.1016/j.crci.2006.12.010